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Samoilenko, Yegor; Wolden, Colin A. (, 2018 IEEE 7th World Conference on Photovoltaic Energy Conversion (WCPEC) (A Joint Conference of 45th IEEE PVSC, 28th PVSEC & 34th EU PVSEC))Development of copper-free ZnTe buffer layers for CdTe-based solar cells is an important avenue for improving stability. Group V elements offer a path towards that goal. This work explores two group V elements, phosphorous and antimony, as candidates for making copper-free p-type ZnTe buffer layer using thermal evaporation. It is found that incorporation of both elements into ZnTe film can easily be done. In addition, as deposited ZnTe films are Te-rich and Cd1-xZnxTe alloys form upon co-evaporation of ZnTe and Cd3P2 , improving crystallinity and stoichiometry of the film. Activation of P poses a challenge, while ZnTe films with Sb produced good sheet resistance values.more » « less
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Samoilenko, Yegor; Yeung, Gavin; Munshi, Amit H.; Abbas, Ali; Reich, Carey L.; Walker, Michael; Reese, Matthew O.; Zakutayev, Andriy; Walls, J. Michael; Sampath, Walajabad S.; et al (, Solar Energy Materials and Solar Cells)
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Samoilenko, Yegor; Abbas, Ali; Michael Walls, J.; Wolden, Colin A. (, Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films)
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